170 Search Results

A pioneering machine-learning-based flavor-tagging algorithm combining same-side and opposite-side tagging is used to obtain the equivalent of 27$$\,$$000 tagged B$$^0_\mathrm{s}$$$$\to$$ J/$$\psi\, \phi$$(1020) decays from pp collisions at $$\sqrt{s} =$$ 13 TeV, collected by the CMS experiment and corresponding to an integrated luminosity of 96.5 fb$$^{-1}$$. A time- and flavor-dependent angular analysis of the $$\mu^+\mu^-$$K$$^+$$K$$^-$ final state is used to measure parameters of the $$\mathrm{B}^0_\mathrm{s}$$-$$\overline{\mathrm{B}}^0_\mathrm{s}$$ system. The weak phase is measured to be $$\phi_\mathrm{s}$$ = $$-$$73 $$\pm$$ 23 (stat) $$\pm$$ 7 (syst) mrad, which, combined with a $$\sqrt{s}$$ = 8 TeV CMS result, gives $$\phi_\mathrm{s}$$ = $$-$$74 $$\pm$$ 23 mrad. Thismore » value differs from zero by 3.2 standard deviations, providing evidence for $CP$ violation in B$$^0_\mathrm{s}$$$$\to$$ J/$$\psi\,\phi$$(1020) decays. All measured physics parameters are found to agree with standard model predictions where available.« less

III–VI post-transition-metal chalcogenides are layered semiconductor materials that exhibit direct band gaps in multilayers. Defect engineering is essential in 2D layered semiconductors for functional devices. Here, in this work, we report defect engineering in multilayer gallium selenide (GaSe) and indium selenide (InSe), where defects generated by ultraviolet (UV, 325 nm) laser irradiation result in an additional photoluminescence (PL) line. The additional PL line is due to defect-bound excitons. Characteristics of the defect emission are similar in GaSe and InSe samples subjected to UV irradiation, air annealing, and hydrostatic pressure. Two-beam UV interference was applied to create grating patterns with amore » periodic array of low and high densities of defects in GaSe. Density functional theory has identified the defect type in GaSe. The results provide valuable insights into defect generation and UV scribing of photonic circuits in 2D Se-based multilayers for optical integration in a 2D platform.« less

Strain engineering is one of the most effective routes for tuning the electrical and optical properties of two-dimensional layered materials. Besides reproducing the results of other groups on the tunability and photoluminescence (PL) enhancement of free and bound excitons under mechanical deformation or thermal effects, we systematically studied the mechanical strain (wrinkle) and local thermal strain (laser heating) effects on the PL lifetime and polarization in GaSe multilayers and their interplay, revealing their coupled impact on excitonic dynamics. Here, the PL intensity of localized excitons in the wrinkle region of GaSe increases superlinearly with the excitation laser power. The polarizationmore » effect has been observed for the bound exciton in GaSe under mechanical strain, but not in GaSe under thermal strain. Fluorescence lifetime imaging (FLIM) measurements reveal strain-tunable lifetimes for both free and bound excitons, and the lifetime of the bound exciton is longer than the free exciton in the mechanical strain region, correlating with the enhanced emission of the bound exciton. These results highlight previously uncharacterized optoelectronic tunability in GaSe and broaden the design space for strain (or thermally)-controlled 2D layered devices.« less

Light emission in the solid state is central for illumination, sensing, and imaging applications. Unlike luminescence in dilute solutions, where the excited states are unimolecular in nature, intermolecular interaction plays a significant role in the quantum yield of solid-state luminophores, manifested as competing aggregation-caused quenching (ACQ) and aggregation-induced enhancement (AIE). Both effects are extensively studied in various systems; however, it remains unclear how their competition depends on molecular conformation and intermolecular stacking. Here the direct observation of pressure-modulated AIE-ACQ competition in a crystalline hydrogen-bonded organic framework (HOF) is reported. Using in situ spectroscopies and computational modeling, the intramolecular vibration andmore » intermolecular π–π stacking directly responsible for the non-radiative decay of the excited state are identified. The extent of these two contributions is modulated by hydrostatic pressure and guest molecules in the HOF pores. Furthermore, this work demonstrates a physically neat model system to understand and control solid-state luminescence, and a potential material platform for piezoluminescent sensing.« less

In this work, we report on defect generation in multilayer GaSe through hydrostatic pressure quenching and UV laser irradiation. The Raman line width from the UV 266 nm irradiated sample is much wider than that in pressure-quenched GaSe, corresponding to a wider defect energy distribution range in the former sample than the latter. After quenching from 11.2 GPa, three photoluminescence (PL) peaks from defect states are observed at 657, 681, and 695 nm at a low temperature of 93 K. Defect-related peaks at 649, 694, 750, and 774 nm also appear in low-temperature PL spectra after UV laser irradiation, withmore » a nonmonotonous intensity dependence on irradiation duration. There are common features in defects produced by these two methods: the PL peaks with the lowest energy are sharp, and their PL intensities increase linearly with the excitation laser power and saturate above a certain excitation laser power. These two features are similar to those in defects for single-photon emission (SPE) in other 2D materials at even lower temperatures. Fluorescence lifetime imaging shows distinguished short (2.3 ns) and long (75.6 nm) lifetimes of the 695 nm PL line in pressure-quenched GaSe. The density functional theory predicts defect energy levels related to Se vacancy.« less

A measurement of the top quark pair ($$ \textrm{t}\overline{\textrm{t}} $$) production cross section in proton-proton collisions at a centre-of-mass energy of 5.02 TeV is presented. The data were collected at the LHC in autumn 2017, in dedicated runs with low-energy and low-intensity conditions with respect to the default configuration, and correspond to an integrated luminosity of 302 pb$$^{−1}$$. The measurement is performed using events with one electron or muon, and multiple jets, at least one of them being identified as originating from a b quark (b tagged). Events are classified based on the number of all reconstructed jets and ofmore » b-tagged jets. Multivariate analysis techniques are used to enhance the separation between the signal and backgrounds. The measured cross section is $$ 62.5\pm 1.6{\left(\textrm{stat}\right)}_{-2.5}^{+2.6}\left(\textrm{syst}\right)\pm 1.2\left(\textrm{lumi}\right) $$ pb. A combination with the result in the dilepton channel based on the same data set yields a value of 62.3 ± 1.5 (stat) ± 2.4 (syst) ± 1.2 (lumi) pb, to be compared with the standard model prediction of $$ {69.5}_{-3.7}^{+3.5} $$ pb at next-to-next-to-leading order in perturbative quantum chromodynamics.« less

A search is presented for rare decays of the Z and Higgs bosons to a photon and a J∕ψ or a ψ(2S) meson, with the charmonium state subsequentially decaying to a pair of muons. The data set corresponds to an integrated luminosity of 123 fb⁻¹ of proton-proton collisions at a center-of-mass energy of 13TeV collected with the CMS detector at the LHC. No evidence for branching fractions of these rare decay channels larger than predicted in the standard model is observed. Upper limits at 95% confidence level are set: $$\mathcal{B}$$(H → J∕ψγ ) < 2.6 × 10⁻⁴, $$\mathcal{B}$$(H → ψ(2S)γmore » ) < 9.9 × 10⁻⁴, $$\mathcal{B}$$(Z → J∕ψγ ) < 0.6 × 10⁻⁶, and $$\mathcal{B}$$(Z → ψ(2S)γ ) < 1.3 × 10⁻⁶. The ratio of the Higgs boson coupling modifiers 𝜅_c∕𝜅_γ is constrained to be in the interval (−157, +199) at 95% confidence level. Assuming 𝜅_γ = 1, this interval becomes (−166, +208).« less

Measurements are presented of inclusive and differential cross sections for Z boson associated production of top quark pairs ($$ \textrm{t}\overline{\textrm{t}}\textrm{Z} $$) and single top quarks (tZq or tWZ). The data were recorded in proton-proton collisions at a center-of-mass energy of 13 TeV, corresponding to an integrated luminosity of 138 fb$$^{−1}$$. Events with three or more leptons, electrons or muons, are selected and a multiclass deep neural network is used to separate three event categories, the $$ \textrm{t}\overline{\textrm{t}}\textrm{Z} $$ and tWZ processes, the tZq process, and the backgrounds. A profile likelihood approach is used to unfold the differential cross sections, tomore » account for systematic uncertainties, and to determine the correlations between the two signal categories in one global fit. The inclusive cross sections for a dilepton invariant mass between 70 and 110 GeV are measured to be 1.14 ± 0.07 pb for the sum of $$ \textrm{t}\overline{\textrm{t}}\textrm{Z} $$ and tWZ, and 0.81 ± 0.10 pb for tZq, in good agreement with theoretical predictions.[graphic not available: see fulltext]« less

A search is presented for a heavy resonance decaying into a Z boson and a Higgs (H) boson. The analysis is based on data from proton-proton collisions at a centre-of-mass energy of 13 TeV corresponding to an integrated luminosity of 138 fb$$^{−1}$$, recorded with the CMS experiment in the years 2016–2018. Resonance masses between 1.4 and 5 TeV are considered, resulting in large transverse momenta of the Z and H bosons. Final states that result from Z boson decays to pairs of electrons, muons, or neutrinos are considered. The H boson is reconstructed as a single large-radius jet, recoiling againstmore » the Z boson. Machine-learning flavour-tagging techniques are employed to identify decays of a Lorentz-boosted H boson into pairs of charm or bottom quarks, or into four quarks via the intermediate H → WW$$^{*}$$ and ZZ$$^{*}$$ decays. The analysis targets H boson decays that were not generally included in previous searches using the H → $$ \textrm{b}\overline{\textrm{b}} $$ channel. Compared with previous analyses, the sensitivity for high resonance masses is improved significantly in the channel where at most one b quark is tagged.[graphic not available: see fulltext]« less

Nonsymmetrical oxygen-bridged binuclear copper centers have been proposed and modeled as intermediates and transition states in several C–H oxidation pathways, leading to the postulation that structural dissymmetry enhances the reactivity of the bridging oxygen. However, experimentally characterizing the structure and reactivity of these transient species is remarkably challenging. Here, we report the high-pressure synthesis of a metastable nonsymmetrical dicopper-μ-oxo compound with exceptional reactivity toward the mono-oxygenation of aliphatic C–H bonds. The nonequivalent coordination environment of copper stabilizes localized mixed valency and greatly enhances the hydrogen atom abstraction activity of the bridging oxygen, enabling room-temperature hydroxylation of methane under pressure. Thesemore » findings highlight the role of dissymmetry in the reactivity of binuclear copper centers and demonstrate precise control of molecular structures by mechanical means.« less